Direct synthesis of ZSM-5 from kaolin and the influence of organic template
DOI:
https://doi.org/10.11113/mjfas.v13n2.652Keywords:
Crystallization time, kaolin, phase transformation, TPABr, TPAOH, ZSM-5Abstract
We investigated the transformation of kaolin to ZSM-5 using hydrothermal synthesis method and the influence of organic template as a structure-directing agent. The formation of ZSM-5 from kaolin occurred via dissolution of kaolin to form amorphous silica. Zeolite-like analcime produced when the hydrothermal treatment was extended to 18 h. We found synergistic effect of using a mixture of TPAOH and TPABr organic template to enhance kaolin dissolution, initiate ZSM-5 formation and inhibit the transformation of ZSM-5 to analcime.
References
D.J. Kim, H.S.Chung, Appl Clay Sci, 24 (2003) 69–77.
P. Wang, B. Shen, D. Shen, T. Peng, J. Gao, Catal Commun. 8 (2007)1452–1456.
D. Prasetyoko, N. Ayunanda, H. Fansuri, D. Hartanto, Z. Ramli, J Math Fund Sci, 44 (2012) 250-262.
H. Tanaka and A. Fujii, Powder Technol, 20 (2009) 473–479.
H. Feng, C. Li, H. Shan, Appl Clay Sci, 42 (2009) 439–445.
F. Pan, X. Lu, Y. Wang, S. Chen, T. Wang, Y. Yan, Microporous Mesoporous Mater,184 (2014) 134–140.
M. Alkan, C. Hopa, Z. Yilmaz, H. Guler, Microporous Mesoporous Mater, 86 (2005)176-184.
E.B.G. Johnson and S.E. Arshad, Appl Clay Sci, 97–98 (2014) 215–221.
V.P. Shiralkar and A. Clearfield, Zeolites, 9 (1989) 363-370.
K. Byrappa and M. Yoshimura, Handbook of Hydrothermal Technology (Noyes Publications, USA), 2013.
R. Karimi, B. Bayati, N.C. Aghdam, M. Ejtemaee, A.A. Babaluo, Powder Technol, 229 (2012) 229-236.
I. Qoniah, D. Prasetyoko, H. Bahruji, S. Triwahyono, A.A. Jalil, Suprapto, Hartati, T.E. Purbaningtias, Appl Clay Sci, 118 (2015) 290-294.
M.M.J. Treacy, J.B. Higgins, R. Von Balloms, Collection of simulated XRD powder patterns for zeolite, 4th edition (Amsterdam: Elsevier), 2001.
S.H. Park, C.H. Chung, G. Seo, Microporous Mesoporous Mater, 155 (2012) 201–207.
C.A. Rios, C.D. Williams, M.A. Fullen, Appl Clay Sci, 42 (2009) 446-454.
C.E.A. Kirschhock, R. Ravishankar, F. Verspeurt, P.J. Grobet, P.A. Jacobs, J.A. Martens, J Phys. Chem, 103 (1999) 4965-4971.
J. Wang, X.L. Wu, J.X.. Wang, C.Z. Liu, Y.M. Lai, Z.K. Hong, Microporous Mesoporous Mater, 155 (2012) 186-191.
F. Hui, C. Yan-hong, L. Chun-yi, S. Hong-hong, In-situ synthesis of ZSM-5 on silica gel and studies on its catalytic activity. J. Fuel Chem. Technol. 36 (2008) 144-150
J.R. Sohn, J. DeCanio Stephen H.J. Lunsford, D.J. O’Donnell, Determination of framework aluminium content in dealuminated y-type zeolites: A comparison based on unit cell size and wavenumber of i.r. Bands, Department of Chemistry 6 (1985) 225-227.
P.M. English, Sedimentary Geology, 143 (2011) 219-244.