Direct synthesis of ZSM-5 from kaolin and the influence of organic template

Authors

  • Didik Prasetyoko Institut Teknologi Sepuluh Nopember (ITS)
  • Rustam Rustam Kandahar University (KU)
  • Ratna Ediati Institut Teknologi Sepuluh Nopember (ITS)
  • Berty Septiyana Institut Teknologi Sepuluh Nopember (ITS)
  • Yusuf Muhammad Zein Institut Teknologi Sepuluh Nopember (ITS)
  • Hasliza Bahruji Cardiff University
  • Imroatul Qoniah Islamic University of Indonesia
  • Hartati Hartati Universitas Airlangga
  • Hadi Nur UniversitiTeknologi Malaysia

DOI:

https://doi.org/10.11113/mjfas.v13n2.652

Keywords:

Crystallization time, kaolin, phase transformation, TPABr, TPAOH, ZSM-5

Abstract

We investigated the transformation of kaolin to ZSM-5 using hydrothermal synthesis method and the influence of organic template as a structure-directing agent.  The formation of ZSM-5 from kaolin occurred via dissolution of kaolin to form amorphous silica. Zeolite-like analcime produced when the hydrothermal treatment was extended to 18 h. We found synergistic effect of using a mixture of TPAOH and TPABr organic template to enhance kaolin dissolution, initiate ZSM-5 formation and inhibit the transformation of ZSM-5 to analcime.

Author Biographies

Didik Prasetyoko, Institut Teknologi Sepuluh Nopember (ITS)

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Rustam Rustam, Kandahar University (KU)

Department of Chemistry, Faculty of Education

Ratna Ediati, Institut Teknologi Sepuluh Nopember (ITS)

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Berty Septiyana, Institut Teknologi Sepuluh Nopember (ITS)

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Yusuf Muhammad Zein, Institut Teknologi Sepuluh Nopember (ITS)

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Hasliza Bahruji, Cardiff University

Cardiff Catalysis Institute

Imroatul Qoniah, Islamic University of Indonesia

Department of Environmental Engineering, Faculty of Civil and Planning Engineering

Hartati Hartati, Universitas Airlangga

Department of Chemistry, Faculty of Science and Technology

Hadi Nur, UniversitiTeknologi Malaysia

IbnuSina Institute for Fundamental Science Studies, 

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Published

19-06-2017