Direct synthesis of ZSM-5 from kaolin and the influence of organic template

Authors

  • Didik Prasetyoko Institut Teknologi Sepuluh Nopember (ITS)
  • Rustam Rustam Kandahar University (KU)
  • Ratna Ediati Institut Teknologi Sepuluh Nopember (ITS)
  • Berty Septiyana Institut Teknologi Sepuluh Nopember (ITS)
  • Yusuf Muhammad Zein Institut Teknologi Sepuluh Nopember (ITS)
  • Hasliza Bahruji Cardiff University image/svg+xml
  • Imroatul Qoniah Islamic University of Indonesia image/svg+xml
  • Hartati Hartati Airlangga University image/svg+xml
  • Hadi Nur UniversitiTeknologi Malaysia

DOI:

https://doi.org/10.11113/mjfas.v13n2.652

Keywords:

Crystallization time, kaolin, phase transformation, TPABr, TPAOH, ZSM-5

Abstract

We investigated the transformation of kaolin to ZSM-5 using hydrothermal synthesis method and the influence of organic template as a structure-directing agent.  The formation of ZSM-5 from kaolin occurred via dissolution of kaolin to form amorphous silica. Zeolite-like analcime produced when the hydrothermal treatment was extended to 18 h. We found synergistic effect of using a mixture of TPAOH and TPABr organic template to enhance kaolin dissolution, initiate ZSM-5 formation and inhibit the transformation of ZSM-5 to analcime.

Author Biographies

  • Didik Prasetyoko, Institut Teknologi Sepuluh Nopember (ITS)
    Department of Chemistry, Faculty of Mathematics and Natural Sciences
  • Rustam Rustam, Kandahar University (KU)
    Department of Chemistry, Faculty of Education
  • Ratna Ediati, Institut Teknologi Sepuluh Nopember (ITS)
    Department of Chemistry, Faculty of Mathematics and Natural Sciences
  • Berty Septiyana, Institut Teknologi Sepuluh Nopember (ITS)
    Department of Chemistry, Faculty of Mathematics and Natural Sciences
  • Yusuf Muhammad Zein, Institut Teknologi Sepuluh Nopember (ITS)
    Department of Chemistry, Faculty of Mathematics and Natural Sciences
  • Hasliza Bahruji, Cardiff University
    Cardiff Catalysis Institute
  • Imroatul Qoniah, Islamic University of Indonesia
    Department of Environmental Engineering, Faculty of Civil and Planning Engineering
  • Hartati Hartati, Airlangga University
    Department of Chemistry, Faculty of Science and Technology
  • Hadi Nur, UniversitiTeknologi Malaysia
    IbnuSina Institute for Fundamental Science Studies, 

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Published

19-06-2017

Issue

Vol. 13 No. 2 (2017): April - June

Section

Article

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