A Review on Synthesis and Physicochemical Properties-Photocatalytic Activity Relationships of Carbon Quantum Dots Graphitic Carbon Nitride in Reduction of Carbon Dioxide

Authors

  • Siti Hajar Alias Advanced Material for Environmental Remediation (AMER) Research Group, Faculty of Applied Sciences, Universiti Teknologi MARA Cawangan Negeri Sembilan Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, Malaysia
  • Nur Farisha Balqis Ya’akop Advanced Material for Environmental Remediation (AMER) Research Group, Faculty of Applied Sciences, Universiti Teknologi MARA Cawangan Negeri Sembilan Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, Malaysia
  • Nurul Najidah Mohamed UniSZA Science and Medicine Foundation Centre, Universiti Sultan Zainal Abidin, Gong Badak Campus, 21300 Kuala Nerus, Terengganu, Malaysia
  • Nur Nazzatul Azzin Ahmad Tarmizi Advanced Material for Environmental Remediation (AMER) Research Group, Faculty of Applied Sciences, Universiti Teknologi MARA Cawangan Negeri Sembilan Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, Malaysia
  • Sheikh Ahmad Izaddin Sheikh Mohd Ghazali Material, Inorganic, and Oleochemistry (MaterInoleo) Research Group, School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA Cawangan Negeri Sembilan, Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, Malaysia
  • Hadi Nur Center of Advanced Materials for Renewable Energy (CAMRY), Universitas Negeri Malang, Malang 65145, Indonesia

DOI:

https://doi.org/10.11113/mjfas.v19n6.3224

Keywords:

Carbon quantum dots, graphitic carbon nitride, physicochemical properties, photocatalytic activity, relationship, reduction carbon dioxide

Abstract

Carbon dioxide (CO2) is a major greenhouse gas present in over half of the Earth's atmosphere. Elevated CO2 emissions in the atmosphere have become a global warming issue due to the excessive use of fossil fuels by human activities.  Converting CO2 into a useful compound is crucial since CO2 exists in the environment and must be reduced. The use of semiconductor materials in photocatalysis is the best solution to degrade and potentially convert CO2 into a useful energy source. Recently, research on graphitic carbon nitride (g-C3N4) has developed interest due to its phenomenal properties, such as effective charge separation and charge carrier lifetime, electron-hole recombination, and high surface area. CQDs/g-C3N4 has recently emerged as a novel technology due to its excellent physical and chemical properties, especially in the reduction of CO2. Thus, this review outlines the recent modification of graphitic carbon nitride (g-C3N4) by carbon quantum dots (CQDs), which include the synthesis of CQDs/g-C3N4 for CO2 reduction. Lastly, the review discusses physicochemical properties-photocatalytic activity relationship of CQDs/g-C3N4 in the photocatalytic reduction of CO2. This review provides a wide range of perspectives and a guideline for designing the more effective CQDs/ g-C3N4 for photocatalytic reduction of CO2.

References

Adedoyin, F., Ozturk, I., Abubakar, I., Kumeka, T., Folarin, O. and Bekun F. V. (2020). Structural breaks in CO2 emissions: Are they caused by climate change protests or other factors? Journal of Environmental Management, 266(December 2019), 110628.

Mgolombane, M., Majodina, S., Bankole, O. M., Ferg, E. E. and Ogunlaja, A. S. (2021). Influence of surface modification of zinc oxide–based nanomaterials on the photocatalytic reduction of carbon dioxide. Materials Today Chemistry, 20, 100446.

Asadzadeh-Khaneghah, S. and Habibi-Yangjeh, A. (2020). G-C3N4/carbon dot-based nanocomposites serve as efficacious photocatalysts for environmental purification and energy generation: A review. Journal of Cleaner Production, 276, 124319.

Adekoya, D. O., Tahir, M. and Amin, N. A. S. (2017). G-C3N4/(Cu/TiO2) nanocomposite for enhanced photoreduction of CO2 to CH3OH and HCOOH under UV/visible light. Journal of CO2 Utilization, 18, 261-74.

Mkhalid, I. A., Mohamed, R. M., Ismail, A. A. and Alhaddad, M. (2021). Z-scheme g-C3N4 nanosheet photocatalyst decorated with mesoporous CdS for the photoreduction of carbon dioxide. Ceramics International. February.

Zhang, Z. W., Guo, R. T., Tang, J. Y., Miao, Y. F., Gu, J. W. and Pan, W. G. (2021). Fabrication of Bi-BiOCl/MgIn2S4 heterostructure with step-scheme mechanism for carbon dioxide photoreduction into methane. Journal of CO2 Utilization, 45(January), 101453.

Kumar, A., Prajapati, P. K., Aathira, M. S., Bansiwal, A., Boukherroub, R. and Jain, S. L. (2019). Highly improved photoreduction of carbon dioxide to methanol using cobalt phthalocyanine grafted to graphitic carbon nitride as photocatalyst under visible light irradiation. Journal of Colloid and Interface Science, 543, 201-13.

Adekoya, D., Tahir, M. and Amin, N. A. S. (2019). Recent trends in photocatalytic materials for reduction of carbon dioxide to methanol. Renewable and Sustainable Energy Reviews, 116(May 2018), 109389.

Harun, M., Ahmad, S. A., Sulaiman, N. and Tria, D. (2021). Sectoral energy-CO2 emissions using an environmental input-output framework. International Journal of Business and Society, 22(2), 1066-75.

Nafis Zain Safwan Majid Zain and Umar Izat Nubli. (2022). Malaysia: The laws relating to zero emissions in Malaysia.

Hong, Y., Meng Y., Zhang, G., Yin, B., Zhao, Y., Shi, W. and Li, C. (2016). Facile fabrication of stable metal-free CQDs/g-C3N4 heterojunctions with efficiently enhanced visible-light photocatalytic activity. Separation and Purification Technology, 171, 229-37.

Li, D., Hussain, S., Wang, Y., Huang, C., Li, P., Wang, M. and He, T. (2021). ZnSe / CdSe Z-scheme composites with Se vacancy for efficient photocatalytic CO2 reduction. Applied Catalysis B: Environmental. 286(December 2020), 119887.

Li, H., Huang, G., Xu, H., Yang, Z., Xu, X., Li, J., Qu, A. and Chen, Y. (2020). Enhancing photodegradation activity of g-C3N4 via decorating with S-doped carbon nitride quantum dots by in situ polymerization. Journal of Solid State Chemistry, 292(July), 121705.

Rakibuddin, M. and Kim, H. (2019). Reduced graphene oxide supported C3N4 nanoflakes and quantum dots as metal-free catalysts for visible light assisted CO2 reduction. Beilstein Journal of Nanotechnology, 10(1), 448-58.

Chen, Y. and Bai, X. (2020). A review on quantum dots modified g-C3N4-based photocatalysts with improved photocatalytic activity. Catalysts, 10(1).

Hasan, M. R., Saha, N., Quaid, T. and Reza, M. T. (2021). Formation of carbon quantum dots via hydrothermal carbonization: investigate the effect of precursors. Energies, 14(4), 986.

Wang, Y. and Hu, A. (2014). Carbon quantum dots: Synthesis, properties and applications. Journal of Materials Chemistry C, 2(34), 6921-39.

Tai, J. Y., Leong, K. H., Saravanan, P. and Sim, L. C. (2018). Bioinspired synthesis of carbon dots / g-C3N4 nanocomposites for photocatalytic application. In: E3S Web of Conferences, 1-7.

Zhou, J., Tian, Y., Wu, X. and Hou, X. (2017). Visible light photochemical vapor generation using metal-free g-C3N4/CQDs composites as catalyst: Selective and ultrasensitive detection of mercury by ICP-MS. Microchemical Journal, 132, 319-26.

Liang, H., Li, T., Zhang, J., Zhou, D., Hu, C., An, X., Liu, R. and Liu, H. (2019). 3-D hierarchical Ag/ZnO@CF for synergistically removing phenol and Cr(VI): Heterogeneous vs. homogeneous photocatalysis. Journal of Colloid and Interface Science, 558, 85-94.

Tariq, M., Muhammad, M., Khan, J., Raziq, A., Uddin, M. K., Niaz, A., Ahmed, S. S. and Rahim, A. (2020). Removal of rhodamine B dye from aqueous solutions using photo-Fenton processes and novel Ni-Cu@MWCNTs photocatalyst. Journal of Molecular Liquids, 312, 113399.

Pavlopoulos, N. G. (2021). Shining light on the role of shape-controlled nanomaterials in photocatalysis. Current Opinion in Electrochemistry, 26, 100676.

Kulandaivalu, T., Mohamed, A. R., Ali, K. A. and Mohammadi, M. (2020). Photocatalytic carbon dioxide reforming of methane as an alternative approach for solar fuel production-a review. Renewable and Sustainable Energy Reviews, 134(August), 110363.

Kanakaraju, D., Glass, B. D. and Oelgemöller, M. (2013). Heterogeneous photocatalysis for pharmaceutical wastewater treatment, 69-133.

Zhang, F., Wang, X., Liu, H., Liu, C., Wan, Y., Long, Y. and Cai, Z. (2019). Recent advances and applications of semiconductor photocatalytic technology. Applied Sciences (Switzerland), 9(12).

Hu, G., Yang, J., Duan, X., Farnood, R., Yang, C., Yang, J., Liu, W. and Liu, Q. (2021). Recent developments and challenges in zeolite-based composite photocatalysts for environmental applications. Chemical Engineering Journal, 417(December 2020), 129209.

Yusuf, M., Song, S., Park, S. and Park, K. H. (2021). Multifunctional core-shell Pd@Cu on MoS2 as a visible light-harvesting photocatalyst for synthesis of disulfide by S[sbnd]S coupling. Applied Catalysis A: General, 613(November 2020), 118025.

Alias, S. H., Mohamed, N., Loon, W. and Chandren, S. (2019). Synthesis of carbon self-doped titanium dioxide and its activity in the photocatalytic oxidation of styrene under visible light irradiation, Malaysian Journal of Fundamental and Applied Sciences.

Ibrahim, N. S., Leaw, W. L., Mohamad, D., Alias, S. H. and Nur, H. (2020). A critical review of metal-doped TiO2 and its structure–physical properties–photocatalytic activity relationship in hydrogen production. International Journal of Hydrogen Energy, 45(53), 28553-65.

Karamian, E. and Sharifnia, S. (2016). On the general mechanism of photocatalytic reduction of CO2. Journal of CO2 Utilization. 16, 194-203.

Karamian, E. and Sharifnia, S. (2016). On the general mechanism of photocatalytic reduction of CO2. Journal of CO2 Utilization, 16, 194-203.

Liu, R., Chen, Z., Yao, Y., Li, Y., Cheema, W. A., Wang, D. and Zhu, S. (2020). Recent advancements in g-C3N4-based photocatalysts for photocatalytic CO2 reduction: A mini review. RSC Advances, 10(49), 29408-18.

Ong, W. J., Putri, L. K., Tan, Y. C., Tan, L. L., Li, N., Ng, Y. H., Wen, X. and Chai, S. P. (2017). Unravelling charge carrier dynamics in protonated g-C3N4 interfaced with carbon nanodots as co-catalysts toward enhanced photocatalytic CO2 reduction: A combined experimental and first-principles DFT study. Nano Research, 10(5), 1673-96.

Guo, R. tang, Liu, X. yu, Qin, H., Wang, Z. yi, Shi, X., Pan, W. guo, Fu, Z. guo, Tang, J. ying, Jia, P. yao, Miao, Y. fang and Gu, J. wen. (2020). Photocatalytic reduction of CO2 into CO over nanostructure Bi2S3 quantum dots/g-C3N4 composites with Z-scheme mechanism. Applied Surface Science, 500(October 2019), 144059.

Trivedi, S., Prochowicz, D., Kalam, A., Tavakoli, M. M. and Yadav, P. (2021). Development of all-inorganic lead halide perovskites for carbon dioxide photoreduction. Renewable and Sustainable Energy Reviews, 145(April), 111047.

Ming-Hsien, Chan, Ru-Shi, Liu, M. H. (2019). Graphitic carbon nitride-based nanocomposites and their biological applications: a review. RSC Advances, 11, 14993-5003.

Ajiboye, T. O., Kuvarega, A. T. and Onwudiwe, D. C. (2020). Graphitic carbon nitride-based catalysts and their applications: A review. Nano-Structures and Nano-Objects, 24, 100577.

Qin, J. and Zeng, H. (2017). Photocatalysts fabricated by depositing plasmonic Ag nanoparticles on carbon quantum dots/graphitic carbon nitride for broad spectrum photocatalytic hydrogen generation. Applied Catalysis B: Environmental, 209, 161-73.

Liu, G., Wang, H., Chen, D., Dai, C., Zhang, Z. and Feng, Y. (2019). Photodegradation performances and transformation mechanism of sulfamethoxazole with CeO2/CN heterojunction as photocatalyst. Separation and Purification Technology, 237(October 2019), 116329.

Parwaz, Khan, A. A., Singh, P., Raizada, P. M. A. A. (2021). Converting Ag3PO4/CdS/Fe doped C3N4 based dual Z-scheme photocatalyst into photo- Fenton system for efficient photocatalytic phenol removal Aftab. Journal of Industrial and Engineering Chemistry, 103108.

Ma, X., Hu, C. and Bian, Z. (2020). Hybrid photocatalytic systems comprising a manganese complex anchored on g-C3N4 for efficient visible-light photoreduction of CO2. Inorganic Chemistry Communications, 117(April), 107951.

Sahoo, S. K., Bhattacharya, S. and Sahoo, N. K. (2020). Photocatalytic degradation of biological recalcitrant pollutants: A green chemistry approach. Biointerface Research in Applied Chemistry, 10(2), 5048-60.

Ismael, M. (2020). A review on graphitic carbon nitride (g-C3N4) based nanocomposites: Synthesis, categories, and their application in photocatalysis. Journal of Alloys and Compounds, 846, 156446.

Zhang, Z., Lin, S., Li, X. and Cui, W. (2017). Metal free and efficient photoelectrocatalytic removal of organic contaminants over g-C3N4 nanosheet films decorated with carbon quantum dots. RSC Advances, 7(89), 56335-43.

Zhu, K., Ou-Yang, J., Zeng, Q., Meng, S., Teng, W., Song, Y., Tang, S. and Cui, Y. (2020). Fabrication of hierarchical ZnIn2S4@CNO nanosheets for photocatalytic hydrogen production and CO2 photoreduction. Chinese Journal of Catalysis, 41(3), 454-63.

Li, P. and Li, S. F. Y. (2021). Recent advances in fluorescence probes based on carbon dots for sensing and speciation of heavy metals. Nanophotonics, 10(2), 877-908.

Sheikh Mohd Ghazali, S. A. I., Fatimah, I., Zamil, Z. N., Zulkifli, N. N. and Adam, N. (2023). Graphene quantum dots: A comprehensive overview. Vol. 21, Open Chemistry. De Gruyter Open Ltd.

Wei, Y., Li, X., Zhang, Y., Yan, Y., Huo, P. and Wang, H. (2021). G-C3N4 quantum dots and Au nano particles co-modified CeO2/Fe3O4 micro-flowers photocatalyst for enhanced CO2 photoreduction. Renewable Energy, 17, 756-65.

Sakdaronnarong, C., Sangjan, A., Boonsith, S., Kim, D. C. and Shin, H. S. (2020). Recent developments in synthesis and photocatalytic applications of carbon dots. Catalysts, 10(3).

Liu, X., Tan, T., Que, W., Zhou, H. and Wang, K. (2021). Effect of carbon quantum dots on the photo‐absorption, photo‐response and photoelectrochemical performance of KNb3O8 film photoelectrode. Micro & Nano Letters, 16(2), 181-6.

Tyagi, A., Tripathi, K. M., Singh, N., Choudhary, S. and Gupta, R. K. (2016). Green synthesis of carbon quantum dots from lemon peel waste: Applications in sensing and photocatalysis. RSC Advances, 6(76), 72423-32.

Teymoorian, T., Hashemi, N., Mousazadeh, M. H. and Entezarian, Z. (2021). N, S doped carbon quantum dots inside mesoporous silica for effective adsorption of methylene blue dye. SN Applied Sciences, 3(3).

Ashritha, M. G., Rondiya, S. R., Cross, R. W., Dzade, N. Y., Dhole, S. D., Hareesh, K. and Sunitha, D. V. (2021). Experimental and computational studies of sonochemical assisted anchoring of carbon quantum dots on reduced graphene oxide sheets towards the photocatalytic activity. Applied Surface Science, 545(November 2020), 148962.

Han, Y., Han, Y., Du, G., Zhang, T., Guo, Q., Yang, H., Li, R. and Xu, Y. (2021). Physiological effect of colloidal carbon quantum dots onBursaphelenchus xylophilus. RSC Advances, 11(11), 6212-20.

Tian, L., Li, Z., Wang, P., Zhai, X., Wang, X. and Li, T. (2021). Carbon quantum dots for advanced electrocatalysis. Journal of Energy Chemistry, 55, 279-94.

Hernández-Alonso, J. M. C. and M. D. (2013). The keys of success: TiO2 as a benchmark photocatalyst. Green Energy and Technology, 71, 85-101.

Arumugam, N. and Kim, J. (2018). Synthesis of carbon quantum dots from Broccoli and their ability to detect silver ions. Materials Letters, 219, 37-40.

Feng, H., Guo, Q., Xu, Y., Chen, T., Zhou, Y., Wang, Y., Wang, M. and Shen, D. (2018). Surface nonpolarization of g-C3N4 by decoration with sensitized quantum dots for improved CO2 Photoreduction. ChemSusChem, 11(24), 4256-61.

Wang, Y., Liu, X., Han, X., Godin, R., Chen, J., Zhou, W., Jiang, C., Thompson, J. F., Mustafa, K. B. Shevlin, S. A., Durrant, J. R., Guo, Z. and Tang, J. (2020). Unique hole-accepting carbon-dots promoting selective carbon dioxide reduction nearly 100% to methanol by pure water. Nature Communications, 11(1), 1-9.

Lingyou, Meng, Yang, Qu, L. J. (2021). Recent advances in BiOBr-based photocatalysts for environmental remediation. Chinese Chemical Letters, 105084.

Patial, S., Kumar, R., Raizada, P., Singh, P., Van Le, Q., Lichtfouse, E., Le Tri Nguyen, D., Nguyen V.-H. (2021). Boosting light-driven CO2 reduction towards solar fuels: Mainstream avenues for engineering engineering ZnO-based photocatalysts. Environmental Research, 135907.

Pareek, S., Waheed, S., Rana, A., Sharma, P. and Karak, S. (2020). Graphitic carbon nitride quantum dots (gC3N4) to improve photovoltaic performance of polymer solar cell by combining Förster resonance energy transfer (FRET) and morphological effects. Nano Express, 1(1), 010057.

Li, Q., Wang, S., Sun, Z., Tang, Q., Liu, Y., Wang, L., Wang, H. and Wu, Z. (2019). Enhanced CH4 selectivity in CO2 photocatalytic reduction over carbon quantum dots decorated and oxygen doping g-C3N4. Nano Research, 12(11), 2749-59.

Jo, W. K., Kumar, S. and Tonda, S. (2019). N-doped C dot/CoAl-layered double hydroxide/g-C3N4 hybrid composites for efficient and selective solar-driven conversion of CO2 into CH4. Composites Part B: Engineering, 176(April), 107212.

Feng, C., Zhang, X., Jin, H., Du, R., Wang, Y., Zhou, Y., Chong, R., Liu, X. and Huang, Q. (2023). Integrating carbon vacancy modified carbon quantum dots with carbon nitride for efficient photocatalytic CO2 reduction to syngas with tunable hydrogen to carbon monoxide ratio. Carbon, 203, 671-85.

Liu, W., Wang, Q., Liu, Z. and Ding, G. (2022). Bridging between NiAl-LDH and g-C3N4 by using carbon quantum dots for highly enhanced photoreduction of CO2 into CO. Journal of Colloid and Interface Science. 622, 21-30.

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Published

05-12-2023