Highly Efficient Synthesis of Complex bis-2,4-dimethoxy-1,3,5-triazapentadienemetal(II) (metal = Cu, Ni) with Hirshfeld Surface Analysis

I Wayan Dasna; Husni Wahyu Wijaya; Faaza’izzahaq Setta Putra; Hakam Abdulloh; Ahmad Taufiq

doi:10.11113/mjfas.v19n3.3018

Authors

I Wayan Dasna ᵃDepartment of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145; ᵇCentre of Advanced Material for Renewable Energy, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5 Malang, Jawa Timur, Indonesia 65145
Husni Wahyu Wijaya ᵃDepartment of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145; ᵇCentre of Advanced Material for Renewable Energy, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5 Malang, Jawa Timur, Indonesia 65145
Faaza’izzahaq Setta Putra Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145
Hakam Abdulloh Department of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145
Ahmad Taufiq ᵃDepartment of Chemistry, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145; ᶜDepartment of Physics, State University of Malang (Universitas Negeri Malang), Jl. Semarang 5, Malang, Jawa Timur, Indonesia 65145

DOI:

https://doi.org/10.11113/mjfas.v19n3.3018

Keywords:

Copper(II) complex, nickel(II) complex, 2,4-methoxy-1,3,5-triazapentadiene ligand, solvothermal, Hirshfeld surface analysis

Abstract

The synthesis of copper(II) or Nickel(II) complex with bis-2,4-dimethoxy-1,3,5-triazapentadiene ligand has been reported using a direct reaction and reflux method. These methods take a relatively long synthesis time, so it is necessary to develop a faster synthesis method. This study reports a solvothermal method to synthesize bis-2,4-dimethoxy-1,3,5-triazapentadiene copper(II) and nickel(II) as in situ with sodium dicyanamide and methanol that produces single crystals in a day and two days respectively. XRD analysis of both single crystals from solvothermal results showed a monoclinic crystal lattice and a P21/n space group which was not different from previous studies. The Hirshfeld analysis indicates that the interactions with the most prevelant contributions in both of complexes are H—H, O—H/H—O, and N—H/N—H.

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