Pyrolysis of torrefied oil palm wastes for better biochar
DOI:
https://doi.org/10.11113/mjfas.v13n2.636Keywords:
Torrefaction, Pyrolysis, BiocharAbstract
The objective of this research work is to investigate the effect of torrefaction on the pyrolysis product. Biomass materials such as empty fruit bunch (EFB), mesocarp fibre (MF) and palm shell (PKS) were torrefied and pyrolyzed. The experiment conditions were set to be respectively at 220 o C of temperature, 10 o C/min of heating rate and 30 minutes holding time for torrefaction and at 650 oC of temperature, 20 o C/min heating rate and 2 hours holding time for pyrolysis. Nitrogen flow rate of 2L/min was maintained for both experiments. The torrefied biomass contains high carbon content and low oxygen content than the raw biomass. Also, the biochar derived from torrefied biomass have high fixed carbon content than the biochar derived from untorrefied biomass. The maximum higher heating value (HHV) of about 31.2 MJkg-1 is obtained in the biochar derived from the torrefied shell. Though, all the biomass materials used in this research have exhibited a positive outcome after being torrefied and pyrolyzed. It is clear from scanning electron microscopy (SEM) images that the biochar (b) and (d) derived from torrefied biomass could be better in the application of soil amendment and water retention due to a large number of uniform holes. Therefore, it can be concluded that pyrolysis of torrefied biomass improved the quality of biochar than the biochar obtained from untorrefied biomass.
References
Abdullah, N., Sulaiman, F. 2013. The oil palm wastes in Malaysia. In Matovic, M. D. (Ed.). Biomass Now- Sustainable Growth and Use (pp. 978 – 953). Crotia: InTech. Retrieved from: https://www.intechopen.com/books/biomass-now-sustainable-growth-and-use/the-oil-palm-wastes-in-malaysia.
Abnisa, F., Arami-Niya, A., Daud, W. M. A. W., Sahu, J. N. 2013. Characterization of bio-oil and bio-char from pyrolysis of palm oil wastes. BioEnergy Research, 6, 830-840.
Adisak P., James O. T., Anthony, V. B. 2006. Fast pyrolysis of agricultural residues from cassava plantation for bio-oil production. 2nd Joint International Conference on Sustainable Energy and Environment. 21-23 November 2006. Bangkok, Thailand.
Angin, D. 2013. Effect of pyrolysis temperature and heating rate on biochar obtained from pyrolysis of safflower seed press cake. Bioresource Technology, 128, 593-597.
Awalludin, M. F., Sulaiman, O., Hashim, R. and Nadhari, W. N. A. W. 2015. An overview of the oil palm industry in Malaysia and its waste utilization through thermochemical conversion, specifically via liquefaction. Renewable and Sustainable Energy Reviews, 50, 1469-1484.
Basu, P., Sadhukhan, A. K., Gupta, P., Rao, S., Dhungana, A., Acharya, B. 2014. An experimental and theoretical investigation on torrefaction of a large wet wood particle. Bioresource Technology 159, 215-222.
Chen, W.-H., Hsu, H.-C., Lu, K.-M., Lee, W.-J., Lin, T.-C. 2011. Thermal pretreatment of wood (Lauan) block by torrefaction and its influence on the properties of the biomass. Energy, 36, 3012-3021.
Idris, S. S., Rahman, N. A., Ismail, K. 2012. Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA). Bioresource Technology, 123, 581-591.
Kambo, H. S., Dutta, A. 2015. A comparative review of biochar and hydrochar regarding production, physico-chemical properties, and applications. Renewable and Sustainable Energy Reviews, 45, 359-378.
Medic, D., Darr, M., Shah, A., Potter, B., Zimmerman, J. 2012. Effects of torrefaction process parameters on biomass feedstock upgrading. Fuel, 91, 147-154.
Morali, U., Şensöz, S. 2015. Pyrolysis of hornbeam shell (Carpinus betulus L.) in a fixed bed reactor: Characterization of bio-oil and bio-char. Fuel, 150, 672-678.
Sohi, S., Lopez-Capel, E., Krull, E., Bol, R. 2009. Biochar, climate change, and soil. A review to guide future research. Commonwealth Scientific and Industrial Reseach Organization Land and Water Science Report 05/09. CSIRO, Australia. Retrieved from website: www.csiro.au.
Sukiran, M. A., Chin, C. M., Bakar, N. K. A. 2009. Bio-oils from pyrolysis of oil palm empty fruit bunches. American Journal of Applied Sciences, 6, 869-875.
Sulaiman, F., Abdullah, N., Gerhauser, H., Shariff, A. 2011. An outlook of Malaysian energy, oil palm industry and its utilization of wastes as useful resources. Biomass and Bioenergy, 35, 3775-3786.
Uemura, Y., Omar, W. N., Tsutsui, T., Yusup, S. B. 2011. Torrefaction of oil palm wastes. Fuel, 90, 2585-2591.
Van Der Stelt, M. J. C., Gerhauser, H., Kiel, J. H. A., Ptasinski, K. J. 2011. Biomass upgrading by torrefaction for the production of biofuels: A review. Biomass and Bioenergy, 35, 3748-3762.