Water-soluble chitosan from shrimp and mussel shells as corrosion inhibitor on tinplate in 2% NaCl

Harmami Harmami, Ita Ulfin, Arina Hidayatus Sakinah, Yatim Lailun Ni’mah

Abstract


Water-Soluble Chitosan (WSC) was synthesized form shrimp and mussel shells wastes and used as corrosion inhibitor on tinplate in 2% NaCl. Chitin was extracted from shrimp and mussel shells wastes by demineralization and deproteinization reactions.Chitin was deacetylated to crude chitosan. WSC was obtained by shortening the crude chitosan polymer chain using H2O2. WSC was characterized by FTIR. WSC performance as corrosion inhibitor on tinplate in 2% NaCl was studied by weightloss and potentiodynamic polarization methods. WSC inhibition efficiency was studied in various concentrations from 10-1500 mg/L. Maximum inhibition efficiencies of WSC from shrimp shells waste were 72,73% (weightloss method) and 91,41% (potentiodynamic polarization method), while maximum inhibition efficiency of WSC from mussel shells waste was 54,55% (weightloss method) with the addition of 1300 mg/L WSC concentration. Weightloss studies revealed that WSC acted as mixed type of inhibitor and obeyed Freundlich adsorption isoterm.


Keywords


Tinplate, corrosion inhibitor, water-soluble chitosan, weight loss, potentiodynamic polarization

Full Text:

PDF

References


Aghzzaf, A.A., Rhouta, B., Steinmetz, J., Rocca, E., Aranda, L., Khalil, A., Yvon, J., Daoudi, L. 2012. Corrosion inhibitors based on chitosan-heptanoate modified beidellite. Applied Clay Science, 65-66, 173-178.

Anejjar, A., Salghi, R., Zarrouk, A., Benali, O., Zarrok, H., hammouti, B., Ebenso, E.E. 2014. Inhibition of carbon steel corrosion in 1 M HCl medium by potassium thiocyanate. Journal of the Association of Arab Universities for Basic and Applied Sciences, 15, 22-27.

Anshari, K.R., Quraishi, M.A. 2014. effect of three component (aniline-formaldehyde and piperazine) polymer on mild steel corrosion in hydrochloric acid medium. Journal of the Association of Arab Universities for Basic and Applied Sciences, 18, 12-18.

Arancibia, M.Y., Aleman, A., Calvo, M.M., Lopez-Caballero, M.E., Montero, P., Gomez-Guillen, M.C. 2014. antimicrobial and antioxidant chitosan solutions enriched with active shrimp (Litopenaeus vannamei) waste materials. Food Hydrocolloids, 35, 710-717.

Balaji, J., Sethuraman, M.G. 2017. Chitosan-doped-hybrid/TiO2 nanocomposite based sol-gel coating for the corrosion resistance of aluminum metal in 3,5% NaCl medium. International Journal of Biological Macromolecules, 104.

Bhawsar, J., Jain, P.K., Jain, P. 2015. experimental and computational studies of Nicotiana tabacum leaves extract as green corrosion inhibitor for mild steel in acidic medium. Alexandria Engineering Journal, 54, 769-775.

Catala, R., Cabanes, J.M., Bastidas, J.M. 1998. An impedance study on the corrosion properties of lacquered tinplate cans in contact with tuna and mussels in pickled sauce. Corrosion Science, 40, 1455-1467.

Czechowska-Biskup, R., Jarosińska, D., Rokita, B., Ulański, P., Rosiak, J.M. 2012. Determination of degree of deacetylation of chitosan- Comparison of methods. Progress on Chemistry and Application of Chitin and its Derivatives, 18, 5–20.

Du, Y., Zhao, Y., Dai, S., Yang, B. 2009. Preparation of water-soluble chitosan from shrimp shell and its antibacterial activity. Innovative Food Science and Emerging Technologies, 10, 103-107.

El-Haddad, M. 2013. Chitosan as a green inhibitor for copper corrosion in acidic medium. International Journal of Biological Macromolecules, 55, 142-149.

Firdausi, S., Harmami 2014. Optimasi waktu dan potensial dalam pelapisan kitosan pada tin plate secara elektroforesis. Jurnal Sains dan Seni ITS, 1 No. 1, 1-5.

Ghorbel-Bellaaj, O., Hajji, S., Younes, I., Chaabouni, M., Nasri, M., Jellouli, K.. 2013. Optimization of chitin extraction fron shrimp waste with Bacillus pumilus A1 using response surface methodology. International Journal of Biological Macromolecules, 61, 243-250.

Hamdani, N.E., Fdil, R., Tourabi, M., Jama, C., Bantiss, F. 2015. Alkaloids Extract of Retama monosperma (L.) Boiss. Seeds used as novel eco-friendly inhibitor for carbon steel corrosion in 1 M HCl solution: Electrochemical and surface studies. Applied Surface Science, 357, 1294-1305.

Huang, X., Lang, F., Ma, Y., Chen, Y., Zhang, Z., Zhang, J. 2014. Effects of reflowing temperature and time on alloy layer of tinplate and its electrochemical behavior in 3.5% NaCl solution. Transactions of Nonferrous Metals Society of China, 24, 1978-1988.

Kumari, S., Rath, P., Kumar, A.S.H., Tiwari, T.N. 2015. Extraction and caracterization of chitin and chitosan from fishery waste by chemical method. Environmental Technology & Innovation, 3, 77-85.

Pursetyo, K.T., Purbowati, P., Sulmartiwi, L. 2017. Degree of deacetylation chitosan from pen shell (Atrina pectinata) with multistage deacetylation process. AIP Conference Proceedings, 1813 (1), 020019.

Ramasamy, P., Subhapradha, N., Shanmugam, V., Shanmugam, A. 2014. Extraction, characterization and antioxidant property of chitosan from cuttlebone Sepia kobiensis (Hoyle 1885). International Journal of Biological Macromolecules, 64, 202-212.

Riszki, T.I., Harmami 2015. Pengaruh suhu terhadap kualitas coating (pelapisan) stainless steel Tipe 304 dengan kitosan secara elektroforesis. Jurnal Sains dan Seni ITS, 4 No. 1, 2337-3250.

Ruhi, G., Modi, O.P., Dhawan, S.K. 2015. Chitosan-polypyrrole-SiO2 composite coatings with advanced anticorrosive properties. Synthetic Metals, 200, 24-39.

Saleh, C.W., Harmami, Ulfin, I. 2017. pengendalian korosi menggunakan inhibitor kitosan larut air untuk baja lunak dalam media HCl 1M. Jurnal Sains dan Seni ITS, 6 No. 1, 2337-3250.

Sangeetha, Y., Meenakshi, S., Sundaram, C. S. 2016. Interactions at the mild steel acid solution interface in the presence of O-fumaryl-chitosan: Electrochemical and surface studies. Carbohydrate Polymers, 136, 38–45.

Trethewey, K.R and Chamberlain, J. 1991. Korosi untuk mahasiswa dan rekayasawan. PT Gramedia Pustaka Utama : Jakarta.

Verma, C., Ebenso, E.E., Quraishi, M.A. 2017. ionic liquids as green and sustainable corrosion inhibitors for metals and alloys : An overview. Journal of Molecular Liquids, 233, 403-414.

Wardani, L.A., Harmami. 2014. Optimasi pelapisan SS 304 dengan kitosan secara elektroforesis. Jurnal Sains dan Seni ITS, 1 No. 1, 1-4.

Xia, D., Song, S., Wang, J., Bi, H., Jiang, Y., Han, Z. 2012. Corrosion behavior of tinplate in NaCl Solution. Transactions of Nonferrous Metals Society of China, 22, 717-724.

Yaro, A.S., Khadom, A.A., Wael, R.K. 2013. Apricot juice as green corrosion inhibitor of mild steeel in phosphoric acid. Alexandria Engineering Journal, 52, 129-135.




DOI: https://doi.org/10.11113/mjfas.v15n2.972

Refbacks

  • There are currently no refbacks.


Copyright (c) 2019 Harmami Harmami

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.


Copyright © 2005-2019 Penerbit UTM Press, Universiti Teknologi Malaysia. Disclaimer: This website has been updated to the best of our knowledge to be accurate. However, Universiti Teknologi Malaysia shall not be liable for any loss or damage caused by the usage of any information obtained from this website.