Adsorption study of Congo Red Dye with ZSM-5 directly synthesized from bangka kaolin withouth organic template
DOI:
https://doi.org/10.11113/mjfas.v13n4.934Keywords:
Bangka Kaolin, ZSM-5, Congo Red, Isotherm AdsorptionAbstract
ZSM-5’s adsorption study of kaolin Bangka without organic template using congo red with initial concentration of 50-250 mg / L with variation of contact time of 40-180 minutes. The results of the adsorption of Congo Red (CR) dye at 30oC-50oC with pH 7, the increase in contact time causes the dye to decrease significantly. In addition, an increase in adsorption rate at first step then slows down as it approaches to the equilibrium point. The experimental results using each temperature variation, showing the equilibrium time of the adsorption process at contact time of 100 minutes. Four isotherm adsorption models were used to analyze and measure the results of experimental data adsorption. The ZSM-5 adsorption capacity of Bangka kaolin is exhibited for the reds of Congo isotherm adsorption. The results of isotherm adsorption studies on three temperatures showed the fitting into Langmuir isotherms adsorption type which means the adsroption occured physically monolayer, the kinetics of adsorption clearly follows the first-pseudo-order reaction kinetics with higher R2 closes to 1. The adsorption thermodynamics analysis show that the adsorption chategorized as exthormic reaction (negative value of ), this conclusion is supported by adsortion capacity data in 180 min contact times which demostrate that the increasing adorption temperature decreasing amount adsorbate being adsorbed. The (Gibb’s Energy) of adsorption are negative in several temperature which demonstrates that the adsroption are spontanously occured in ech temperature. The adsorption study can be used as a reference for ZSM-5 adsorption optimization.
References
Bagane, M., Guiza, S., (2000). “Removal of a dye from textile effluents by adsorption”. Ann. Chim. Sci. Mater. 25, pp.615–626.
Imamura, K., Ikeda, E., Nagayasu, T., Sakiyama, T. and Nakanishi, K. (2002). Adsorption Behavior of Methylene Blue and Its Congeners on a Stainless Steel Surface. J. Colloid Interface Sci. Volume 245, 50
McKay, G., El-Geundi, M. and Nasser, M.M. (1997) Adsorp. Sci. Technol. 15, 251
El-Geundi, M. (1997). Adsorbents for Industrial Pollution Control. Adsorp. Sci. Technol. 15, 777
McKay, G. (1992). The Removal of Dye Colours from Aqueous Solutions by Adsorption on Low-cost Materials. J. Chem. Technol. Biotechnol. 32, 759.
Dai, M. (1998). Mechanism of adsorption for dyes on activated carbon. J. Colloid Interface Sci. 198, 6.
Gemeay, A.H., El-Sherbiny, A.S. and Zaki, A. (2002). dsorption and kinetic studies of the intercalation of some organic compounds onto Na+-montmorillonite. J. Colloid Interface Sci. 245, 116.
Parida, S.K. and Mishra, B.K. (1996). Adsorption of Styryl Pyridinium Dyes on Alkali Treated Silica. Indian J. Chem. 37A:618
Holzheu, S. and Hoffmann, H. (2002). dsorption study of cationic dyes having a trimethylammonium anchor group on hectorite using electrooptic and spectroscopic methods. J. Colloid Interface Sci. 245, 16
Perineau, F., Molinier, J. and Gaset, A. (1983). Adsorption de colorants ioniques sur le dechet lainier de carbonisage. Water Res. 17, 559.
D. Prasetyoko, N. Ayunanda, H. Fansuri, D. Hartanto. (2012). Phase transformation of rice husk ash in the synthesis of ZSM-5 without organic template. J. Math. Fund. Sci., 44 A (3) (2012), pp. 250-262
Hartanto, D, Saputro, O, Utomo, WP, Rosyidah, A, Sugiarso, D, Ersam, T, Nur, H & Prasetyoko, D. (2016), 'Synthesis of ZSM-5 directly from Kaolin without organic template: Part-1: Effect of crystallization time' Chemistry - An Asian Journal, vol 28, no. 1, pp. 211-215.
Ojedoku, Adedamola Titi n & Olugbenga Solomon Bello. (2017). Liquid phase adsorption of Congo red dye on functionalized corn cobs, Journal of Dispersion Science and Technology, 38:9, 1285-1294
Langmuir, I., (1918). The adsorption of gases on plane surfaces ofglass, mica and platinum. J. Am. Chem. Soc. 40, 1361–1367.
Ho, Y.S., Mckay, G., Wase, D.A.J., Foster, C.F., (2000). Study of thesorption of divalent metalions onto peat. Ads. Sci. Technol. 18(7), 639–650.
Tarapitakcheevin, P., P. Weerayutsil, and K. Khuanmar. (2013). Adsorption of Acid Dye on Activated Carbon Prepared from Water Hyacinth by Sodium Chloride Activation. GMSARN International Journal, 7: 83 – 90
Freundlich, H.M.F., (1906). Uber die adsorption in losungen.Zeitschrift fur Physikalische Chemie (Leipzig) 57A, 385–470.
Dada, A.O., Olalekan, A.P., Olatunya, A.M., Dada, O., (2012). Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR J. Appl. Chem. 3, 38–45.
Temkin, M. and Pyzhev, V. (1940) Kinetics of Ammonia Synthesis on Promoted Iron Catalysts. Acta Physicochimica URSS, 12, 217-222.
C. Aharoni, M. Ungarish. (1977). Kinetics of activated chemisorption. Part 2. Theoretical models. J. Chem. Soc., Faraday Trans., 73, pp. 456-464
Ananta, S., Saumen, Banerjee., Vijay, Veer. (2015). Adsorption Isotherm, Thermodynamic and Kinetic Study of Arsenic (III) on Iron Oxide Coated Granular Activated Charcoal. Int. Res. J. Environment Sci. (1) 4 : 64-77
Yadav SK, Dixit AK. (2015). Efficient Removal of Cr (VI) from Aqueous Solution onto Palm Trunk Charcoal: Kinetic and Equilibrium Studies. Chem Sci J 6: 114.
Günay, A., Arslankaya, E., Tosun, İ., (2007). Lead removal from aqueous solution by natural and pretreated clinoptilolite: Adsorption equilibrium and kinetics. J. Hazard. Mater. 146, 362–371
Dubinin, M.M., Radushkevich, L.V., (1947). Equation of the characteristic curve of activated charcoal. Proc. Acad. Sci.Phys. Chem. Sect. USSR. 55, 331–333.
Tchobanoglous, G., Burton, F.L., Stensel, H.D., (2003). Wastewater Engineering: Treatment and Reuse, 4th edition. Metcalf &Eddy, McGraw-Hill Companies Inc, New York.
Lagergren, S., (1898). Zurtheorie der sogenannten adsorption gelosterstoffe. KungligaSevenska Vetenskapasakademiens,Handlingar 24, 1–39.
Ho, Y.S., Wang, C.C., (2004). Pseudo-isotherms for the sorption of cadmium ion onto tree fern, Process. Biochem. 39 (6), 759–763.
Ho, Y.S., (2004). Pseudo-isotherms using a second order kinetic expression constant, Adsorpt. J. Int. Adsorpt. Soc. 10 (2), 151–158.
Wong, K. K., Lee, C. K., Low, K. S. and Haron, M. J., (2003). Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions. Chemosphere, 50, 23-28.
Ho, Y.S., (2006), Review of Second-order Models for Adsorption Systems, J. Hazard. Mater., 36, 681-689.
Weber, J.W., Morris, J.C., (1963). Kinetics of adsorption oncarbon from solution. J. Sanitary Eng. Div., ASCE 89, 31–60.
Chabani, B., Amrane, A. and Bensmaili, A. (2006) Kinetic Modeling of the Adsorption of Nitrates by Ion Exchange Resin. Chemical Engineering Journal, 125, 111-117.
Islam, M., Patel, R., (2009). Nitrate sorption by thermally activatedMg/Al chloride hydrotalcite-like compound. J. Hazard. Mater.169, 524–531.
Gupta, S.S. and K.G. Bhattacharyya, (2005). Interaction of metal ions with clays: A case study with Pb (II). Applied Clay Sci., 30: 199-208.
Nisaa S. (2011). Adsorpsi biru metilena pada kaolin dan nanokomposit kaolin TiO2 serta uji sifat fotokatalis. [skripsi]. Bogor: FMIPA IPB
Armaroli T, Simon LJ, Digne M, Montanari T, Bevilacqua M, Valtchev V, Patarin J, Busca G. Effects of crystal size and Si/Al ratio on the surface properties of H-ZSM-5 zeolites. Appl. Catal A Gen. 2006;306:78–84
Mohamed, M., O.A. Fouad, A.A. Ismail, I.A. Ibrahim. (2005). Influence of crystallization times on the synthesis of nanosized ZSM-5, In Materials Letters, Volume 59, Issue 27.
Somani, O. G,. Anant L. Choudhari, Bandaru Sarva Rao, S.P. Mirajkar. (2006). Enhancement of crystallization rate by microwave radiation: Synthesis of ZSM-5. Journal of Materials Chemistry and Physics 82(3):538-545.
Adamson, A.W., (1990), Physical Chemistry of Surface, 5 th ed, John Willey &. Sons, New York.
Yahya, S.A., Musa, I.E., Amjad, H.E., and Gavin, M.W. (2008). Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon Dyes Pigm., 77: 16–23.
Ajemba, R.O. (2014). Assessing influence of hydrochloric acid leaching on structural changes and bleaching performance of Nigerian clay from Udi Optim. Isotherm Kinet. Stud., 27: 839–854.
Gercel, O., Ozcan, A., Ozcan, A.S., and Gercel, H.F. (2007). Preparation of activated carbon from a renewable bio-plant of Euphorbia rigida by H2SO4 activation and its adsorption behavior in aqueous solutions. Appl. Surf. Sci., 253: 4843–4852
Wu, F.C., Tseng, R.I., and Jung, R.S. (2001). Kinetic modeling of liquid-phase adsorption of Reactive dyes and metal ions on chitosan Water Res., 35: 613–618.
Harni, Muhammad Rudy, Ani Iryani, Hilman Affandi. (2013). Pemanfaatan serbuk gergaji kayu jati (tectona grandis l.f.) Sebagai adsorben logam timbal (pb).
Venkata, S., Mohan, N., Rao, C., and Karthikeyan, J. (2002). Adsorptive removal of direct azo dye from aqueous phase onto coal based sorbents: a kinetic and mechanistic study J. Hazard. Mater., 90: 189–204.
Bello, O.S., Tan, T.S., and Ahmad, M.A. (2011). Utilization of Cocoa Pod Husk for the Removal of Remazol Black B Reactive Dye from Aqueous Solutions: Kinetic, Equilibrium and Thermodynamic Studies Asia-Pac. J. Chem. Eng., 7: 378–388.
Tan, I.A.W., Ahmad, A.L., and Hameed, B.H. (2008). Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: equilibrium, kinetic and thermodynamic studies Desalination, 225: 13–28.
