Preparation and characterization of PTFE flat sheet membrane: Effect of sodium benzoate content

Authors

  • Faezeah Abd Ghani Universiti Teknologi Malaysia
  • Khaidir Hamzah Universiti Teknologi Malaysia
  • Wan Norharyati Wan Salleh UNIVERSITI TEKNOLOGI MALAYSIA
  • Hasimah Mohamed MALAYSIAN NUCLEAR AGENCY

DOI:

https://doi.org/10.11113/mjfas.v0n0.558

Abstract

Polytetrafluoroethylene (PTFE) flat sheet membranes were prepared through casting and sintering methods. The effect of sodium benzoate salt on the characteristics of PTFE flat sheet membranes such as  morphology, surface roughness, porosity, mechanical strength and crystallinity were studied through scanning electron microscopy (SEM), atomic force microscopy (AFM), mercury intrusion porosimetry, tensile test and X-ray diffraction (XRD). SEM analysis confirmed the formation of irregular porous microstructures in sponge-like configuration. All the fabricated membranes exhibited narrow pore size distributions and have relatively small average pore diameters between 0.074 and 1.068 µm despite having porosity between 36.41 and 74.32 %. In addition, the roughness of the PTFE flat sheet membranes increased as the sodium benzoate content increased. Increasing sodium benzoate content was positive for pore size, porosity and roughness but negative for surface roughness and mechanical properties. This research confirmed that the addition of sodium benzoate salt in aqueous PTFE solution is a useful approach for the fabrication of porous PTFE flat sheet membranes

Author Biographies

Faezeah Abd Ghani, Universiti Teknologi Malaysia

Advance Membrane Technology Research Centre (AMTEC)

Khaidir Hamzah, Universiti Teknologi Malaysia

UTM-MPRC Institute for Oil and Gas

Wan Norharyati Wan Salleh, UNIVERSITI TEKNOLOGI MALAYSIA

Advance Membrane Technology Research Centre (AMTEC)

Hasimah Mohamed, MALAYSIAN NUCLEAR AGENCY

Radiation Processing Technology Division

References

Alto, P., Mark, C. and Anderson, P. E. (1980). United States Patent No. 4,196,070. Pleasanton California: Nuclepore Corporation.

Bakhtiari, L., Javadpour, J., Rezaie, H. R., Erfan, M. and Shokrgozar, M. A. 2015. The effect of swelling agent on the pore characteristics of mesoporous hydroxyapatite nanoparticles. Progress in Natural Science: Materials International, 25(3), 185–190.

Bowen, W. R., Hilal, H., Lovitt, R. W. and Wright, C. J. 1999. Atomic Force Microscope Studies of Membrane Surfaces. In: Sorensen T. S. (Ed.) Surface chemistry and electrochemistry of membranes. Surfactant Science Series, Vol 79 (p1). New York: Dekker.

Fang, Z., Hao, L., Yang, H., Xie, X., Qiu, Y. and Edmund, K. 2009. Polytetrafluoroethylene surface modification by filamentary and homogeneous dielectric barrier discharges in air. Applied Surface Science, 255(16), 7279–7285.

Huang, L., Hsu, P. and Kuo, C. 2008. Pore size control of PTFE membranes by stretch operation with asymmetric heating system. Desalination, 233(1-3), 64–72.

Huang, Y., Huang, Q., Liu, H., Zhang, C., You, Y., Li, N. and Xiao, C. 2017. Journal of Membrane Science, 523(399), 317–326.

Huang, Q., Xiao, C., Feng, X. and Hu, X. 2013. Design of super-hydrophobic microporous polytetrafluoroethylene membrane. New Journal Chemistry, 373-379.

Khadijah, S. and Harun, Z. 2016. Chemical Engineering research and design preparation and characterization of low cost porous ceramic membrane support from kaolin using phase inversion/sintering technique for gas separation : Effect of kaolin content and non-solvent coagulant bath. Chemical Engineering Research and Design, 112, 24–35.

Kurumada, K., Kitamura, T., Fukumoto, N. and Oshima, M. 1998. Structure generation in PTFE porous membranes induced by the uniaxial and biaxial stretching operations, Journal of Membrane Science, 149, 51–57.

Lai, C., Liou, R., Chen, S., Huang, G., & Lee, K. 2011. Preparation and characterization of plasma-modified PTFE membrane and its application in direct contact membrane distillation. Desalination, 267(2-3), 184–192.

Lennerz, B. S., Vafai, S. B., Delaney, N. F., Clish, C. B., Deik, A. A., Pierce, K. A., Mootha, V. K. 2015. Effects of sodium benzoate , a widely used food preservative , on glucose homeostasis and metabolic profiles in humans. Molecular Genetics and Metabolism, 114(1), 73–79.

Lin, A., Shao, S., Li, H., Yang, D., Kong, Y. 2011. Preparation and characterization of a new negatively charged polytetrafluoroethylene membrane for treating oilfield wastewater. Journal of Membrane Science, 371(1-2), 286–292.

Nittami, T., Hitomi, T., Matsumoto, K., Nakamura, K., Ikeda, T., Setoguchi, Y., Motoori, M. 2012. Comparison of Polytetrafluoroethylene flat-sheet membranes with different pore sizes in application to submerged Membrane Bioreactor, 228–236.

Ohya, H., Kudryavtsev, V.V., Semenova, S.I. 1996. Polyimide Membranes: Application, Fabrications and Properties (1st ed.) Tokyo.: Kodansha Ltd.

Qiu, J., Ni, J., Ã, M. Z., Peng, J., Zhou, H., Li, J., Wei, G. 200). Radiation grafting of styrene and maleic anhydride onto PTFE membranes and sequent sulfonation for applications of vanadium redox battery, Radiation Physics and Chemistry, 76, 1703–1707.

Ramya, K., Velayutham, G., Subramaniam, C. K., Rajalakshmi, N., Dhathathreyan, K. S. 2006. Effect of solvents on the characteristics of Nafion ® / PTFE composite membranes for fuel cell applications, Journal of Power Sources, 160, 10–17.

Ranjbarzadeh-dibazar, A., Shokrollahi, P., Barzin, J., Rahimi, A. 2014. Lubricant facilitated thermo-mechanical stretching of PTFE and morphology of the resulting membranes. Journal of Membrane Science, 470, 458–469.

Wang, S., Li, J., Suo, J., Luo, T. 2010. Surface modification of porous poly(tetrafluoraethylene) film by a simple chemical oxidation treatment. Applied Surface Science, 256(7), 2293–2298.

Xiong, J., Huo, P., Ko, F. K., Introduction, I. 2009. Fabrication of ultrafine fibrous polytetrafluoroethylene porous membranes by electrospinning. Journal Materials Research Society, 2755–2761.

Yoo, H., Kwak, S. 2013. Surface functionalization of PTFE membranes with hyperbranched poly (amidoamine) for the removal of Cu 2+ ions from aqueous solution. Journal of Membrane Science, 448, 125–134.

Zhang, G., Ma, Y. 2013. Spectroscopic studies on the interaction of sodium benzoate , a food preservative, with calf thymus DNA. Food Chemistry, 141(1), 41–47.

Zhu, H., Wang, H., Wang, F., Guo, Y., Zhang, H. 2013. Preparation and properties of PTFE hollow fi ber membranes for desalination through vacuum membrane distillation. Journal of Membrane Science, 446, 145–153.

Zubir, N. A., Ismail, A. F. 2002. Effect of sintering temperature on the morphology and mechanical properties of PTFE membranes as a base substrate for proton exchange membrane. Songklanakarin Journal Science Technology, 823-831.

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Published

26-12-2017