Two-Stage Adsorber Design for Methylene Blue Removal by Coconut Shell Activated Carbon

Authors

  • Fadina Amran Universiti Teknologi Malaysia
  • Nur Fatiah Zainuddin Universiti Teknologi Malaysia
  • Muhammad Abbas Ahmad Zaini Universiti Teknologi Malaysia

DOI:

https://doi.org/10.11113/mjfas.v17n6.2303

Keywords:

Activated carbon, adsorption, methylene blue, optimization, two-stage adsorber

Abstract

The present work was aimed at evaluating the performance of two-stage adsorber for methylene blue removal by coconut shell activated carbon in minimizing the adsorbent mass and contact time. The Langmuir constants were used to evaluate the optimum mass, while the pseudo-second-order constants for contact time. Results show that the adsorbent mass can only be minimized by 0.01 % due to the high adsorbent affinity towards methylene blue, while the contact time has been optimized to 12.2 min at the studied conditions. The effect of adsorbent affinity in two-stage adsorber was analyzed to shed some light about its importance in the design of two-stage adsorber. The performance evaluation was also discussed to bring insight into wastewater treatment applications.

Author Biography

Muhammad Abbas Ahmad Zaini, Universiti Teknologi Malaysia

Department of Chemical Engineering

Faculty of Chemical & Energy Engineering

Universiti Teknologi Malaysia

References

T. K. Hoe, “The current scenario and development of the coconut industry,” The Planter, vol. 94, no. 1108, pp. 413-426, 2018.

M. I. M. Masirin, M. B. Ridzuan, S. Mustapha,”An overview of landfill management and technologies: A Malaysian case study at Ampar Tenang,” Proceedings 1st National Seminar on Environment, Development & Sustainability: Ecological, Economical and Social Aspects, Sg. Lang, Selangor, pp. 157-165, 28 – 29 July 2008.

J. Saleem, U. Shahid, M. Hijab, H. Mackey et al., “Production and applications of activated carbons as adsorbents from olive stones,” Biomass Conversion and Biorefinery, vol. 9, pp. 775–802, 2019.

S. W. Seo, Y. J. Choi, J. H. Kim et al., “Micropore‑structured activated carbon prepared by waste PET/ petroleum‑based pitch,” Carbon Letters, vol. 29, no. 4, pp. 385-392, 2019.

Z. Asadi-sangachini, M. M. Galangash, H. Younesi et al., “The feasibility of cost-effective manufacturing activated carbon derived from walnut shells for large-scale CO2 capture,” Environmental Science and Pollution Research, vol. 26, no. 26, pp. 26542-26552, 2019.

O. Boujibar, A. Souikny, F. Ghamouss et al., “CO2 capture using N-containing nanoporous activated carbon obtained from argan fruit shells,” Journal of Environmental Chemical Engineering, vol. 6, no. 2, pp. 1995-2002, 2018.

Y. Lei, R. Huang, L. Guo et al., “Effect of activating agents on the structure and capacitance performance of tofu derived porous carbon, “Journal of Materials Science: Materials in Electronics, vol. 30, pp. 10274-10283, 2019.

H. Wu, R. Chen, H. Du et al., “Synthesis of activated carbon from peanut shell as dye adsorbents for wastewater treatment,” Adsorption Science and Technology, vol. 37, no. 1-2, pp. 34-48, 2018.

J. Baek, H. M. Lee, K. H. An et al., “Preparation and characterization of highly mesoporous activated short carbon fibers from kenaf precursors,” Carbon Letters, vol. 29, no. 4, pp. 393–399, 2019.

R. Ma, X. Qin, Z. Liu et al., “Adsorption property, kinetic and equilibrium studies of activated carbon fiber prepared from liquefied wood by ZnCl2 activation,” Materials, vol. 12, Article ID 12091377, 2019.

A. O. A, E. Naga, M. E Saied, S. A. Shaban et al., “Fast removal of diclofenac sodium from aqueous solution using sugar cane bagasse-derived activated carbon,” Journal of Molecular Liquids, vol. 285, pp. 9-19, 2019.

L. L. Zhi and M. A. A. Zaini, “Potassium carbonate-treated palm kernel shell adsorbent for congo red removal from water,” Jurnal Teknologi, vol. 75, no. 1, pp. 233-239, 2015.

N. Alias, M. A. A. Zaini, M. J. Kamaruddin, “Roles of Impregnation ratio of K2CO3 and NaOH in chemical activation of palm kernel shell,” Journal of Applied Science & Process Engineering, vol. 4, no. 2, pp. 195-204, 2017.

Y. Yasin, M. Z. Hussein, F. Ahmad, “Adsorption of methylene blue onto treated activated carbon,” The Malaysian Journal of Analytical Sciences, vol.11, no. 11, pp. 400 – 406, 2007.

S. Shrestha, G. Son, S. H. Lee et al., “Isotherm and thermodynamic studies of Zn (II) adsorption on lignite and coconut shell-based activated carbon fiber,” Chemosphere, vol. 92, no, 8, pp. 1053-1061, 2013.

R. R. Karri, J. N. Sahu, N. S. Jayakumar, “Optimal isotherm parameters for phenol adsorption from aqueous solutions onto coconut shell based activated carbon: Error analysis of linear and non-linear methods,” Journal of the Taiwan Institute of Chemical Engineers, vol. 80, pp. 472-487, 2017.

O. Oribayo, O. O. Olaleye, A. S. Akinyanju et al., Coconut shell-based activated carbon as adsorbent for the removal of dye from aqueous solution: equilibrium, kinetics, and thermodynamic studies,” Nigerian Journal of Technology, vol. 39, no. 4, pp. 1076 – 1084, 2020.

H. Palanisami, M. R. M. Azmi, M. A. A. Zaini et al., “Coffee residue-based activated carbons for phenol removal,” Water Practice & Technology.

M. Hijab, P. Parthasarathy, H. R. Mackey et al., “Minimizing adsorbent requirements using multi-stage batch adsorption for malachite green removal using microwave date-stone activated carbons,” Chemical Engineering and Processing - Process Intensification, Article ID 108318, 2021.

Markandeya, A. Singh, S.P. Shukla et al., “Adsorptive capacity of sawdust for the adsorption of MB dye and designing of two-stage batch adsorber,” Cogent Environmental Science, vol. 1, no. 1, Article ID 1075856, 2015.

M. A. K. Anuar, N. S. Mahat, N. M. Rusli et al., “Insight into the optimization of mass and contact time in two-stage adsorber design for malachite green removal by coconut shell activated carbon.

F. M. Mohammed, E. P. L. Roberts, A. K. Campen et al., “Wastewater treatment by multi-stage batch adsorption and electrochemical regeneration,” J. Electrochem. Sci. Eng, vol. 2, no. 4, pp. 223-236, 2012.

S. M. S. Bamatraf and M. A. A. Zaini, “Optimization in a two-stage sorption of malachite green by date palm residue carbon.”

Downloads

Published

31-12-2021