Extraction rate of Valuable Compounds from Peanut Skin Waste by Ethanol-Assisted Supercritical Carbon Dioxide: Modelling and Optimization

Authors

  • Nicky Rahmana Putra School of Chemical and Energy Engineering, Universiti Teknologi Malayia, 81310 Johor Bahru, Malaysia
  • Dwila Nur Rizkiyah Centre of Lipid Engineering and Advanced Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310, UTM Johor Bahru, Malaysia
  • Ahmad Hazim Abdul Aziz Faculty of Food Science and Nutrition, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah, Malaysia
  • Zuhaili Idham Centre of Lipid Engineering and Advanced Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310, UTM Johor Bahru, Malaysia
  • Lailatul Qomariyah Department of Industrial Chemical Engineering, Institut Teknologi Sepuluh Nopember, 60111 Surabaya, Surabaya, Indonesia
  • Mohd Azizi Che Yunus Centre of Lipid Engineering and Advanced Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310, UTM Johor Bahru, Malaysia

DOI:

https://doi.org/10.11113/mjfas.v18n2.2237

Keywords:

Peanut skin, Phenolic, Flavonoid, Supercritical Carbon Dioxide/Ethanol, Extraction

Abstract

Response Surface Methodology (RSM) was employed to optimize the extraction rate of phenolic and flavonoid contents from peanut skin by supercritical carbon dioxide (ScCO2) assisted by ethanol as entrainer. The studied extraction parameters were pressure (10 to 30 MPa), temperature (40 to 70 oC), and the ratio of ethanol (2.5 to 7.5%). Brunner’s and Esquivel’s models were applied to evaluate the extraction rate. The best-operating conditions, in the tested range, were 30 MPa, 40 °C, and 4.64% of ethanol ratio, with a maximum extraction rate of 0.22 mg/g.sec and 0.19 mg/g.sec of the phenolic and flavonoid content, respectively. The findings concluded that higher-pressure condition has a significant impact on the extraction rate of phenolic and flavonoid

References

Putra, N.R., et al., Effect of particle size on yield extract and antioxidant activity of peanut skin using modified supercritical carbon dioxide and soxhlet extraction. Journal of Food Processing and Preservation, 2018. 42(8): p. e13689.

Putra, N.R., et al., Recovery and solubility of flavonoid and phenolic contents from Arachis Hypogea in supercritical carbon dioxide assisted by ethanol as cosolvent. Journal of Food Processing and Preservation, 2020. 44(10): p. e14768.

Chanda, S., D. Bhayani, and D. Desai, Polyphenols and flavonoids of twelve Indian medicinal plants. The bioscan, 2013. 8(2): p. 595-601.

Putra, N.R., M.A. Che Yunus, and S. Machmudah, Solubility model of arachis hypogea skin oil by modified supercritical carbon dioxide. Separation Science and Technology, 2019. 54(5): p. 731-740.

Putra, N.R., et al., Comparison extraction of peanut skin between CO2 supercritical fluid extraction and soxhlet extraction in term of oil yield and catechin. Pertanika Journal of Science & Technology, 2018. 26(2).

Radfar, S. and S.M. Ghoreishi, Experimental extraction of L-Carnitine from oyster mushroom with supercritical carbon dioxide and methanol as co-solvent: Modeling and optimization. Journal of Supercritical Fluids, 2018. 140: p. 207-217.

Hrnčič, M.K., et al., Extracts of White and Red Grape Skin and Rosehip Fruit: Phenolic Compounds and their Antioxidative Activity. Acta Chimica Slovenica, 2019.

Garcia-Mendoza, M., et al., Extraction of phenolic compounds and anthocyanins from juçara (Euterpe edulis Mart.) residues using pressurized liquids and supercritical fluids. Journal of Supercritical Fluids, 2017. 119: p. 9-16.

Castro-Vazquez, L., et al., Bioactive flavonoids, antioxidant behaviour, and cytoprotective effects of dried grapefruit peels (Citrus paradisi Macf.). Oxidative medicine and cellular longevity, 2016. 2016.

Bimakr, M., et al., Optimization of Supercritical Carbon Dioxide Extraction of Bioactive Flavonoid Compounds from Spearmint (Mentha spicata L.) Leaves by Using Response Surface Methodology. Food and Bioprocess Technology, 2012. 5(3): p. 912-920.

Putra, N.R., et al., Recovery of valuable compounds from palm-pressed fiber by using supercritical CO2 assisted by ethanol: modeling and optimization. Separation Science and Technology, 2019: p. 1-14.

Putra, N.R., et al., Extraction of peanut skin oil by modified supercritical carbon dioxide: Empirical modelling and optimization. Separation Science and Technology, 2018. 53(17): p. 2695-2703.

Rosli, N.L., et al. Phytochemical analysis and antioxidant activities of Trigona Apicalis propolis extract. in AIP Conference Proceedings. 2016. AIP Publishing.

Silva, F., et al., Physicochemical properties, antioxidant activity and stability of spray-dried propolis. J. ApiProd. ApiMed. Sci., 2011. 3: p. 94-100.

Esquıvel, M., M. Bernardo-Gil, and M. King, Mathematical models for supercritical extraction of olive husk oil. The Journal of Supercritical Fluids, 1999. 16(1): p. 43-58.

Brunner, G., Gas extraction: an introduction to fundamentals of supercritical fluids and the application to separation processes. Vol. 4. 2013: Springer Science & Business Media.

Machmudah, S., et al., Extraction of astaxanthin from Haematococcus p luvialis using supercritical CO2 and ethanol as entrainer. Industrial & engineering chemistry research, 2006. 45(10): p. 3652-3657.

Putra, N.R., et al., Formulation and evaluation of a new semi-empirical model for solubility of plant extracts in supercritical carbon dioxide assisted by ethanol as co-solvent. Chemical Engineering Communications, 2020: p. 1-9.

Peng, W.L., et al., Optimization of process variables using response surface methodology for tocopherol extraction from Roselle seed oil by supercritical carbon dioxide. Industrial Crops and Products, 2020. 143: p. 111886.

Espinosa-Pardo, F.A., et al., Extraction of phenolic compounds from dry and fermented orange pomace using supercritical CO2 and cosolvents. Food and Bioproducts Processing, 2017. 101: p. 1-10.

Adil, I.H., et al., Subcritical (carbon dioxide+ ethanol) extraction of polyphenols from apple and peach pomaces, and determination of the antioxidant activities of the extracts. The journal of supercritical fluids, 2007. 43(1): p. 55-63.

Guo-qing, H., et al., Optimization of conditions for supercritical fluid extraction of flavonoids from hops (Humulus lupulus L.). Journal of Zhejiang University Science B, 2005. 6(10): p. 999.

Duba, K. and L. Fiori, Supercritical CO2 extraction of grape seeds oil: scale-up and economic analysis. International Journal of Food Science & Technology, 2019. 54(4): p. 1306-1312.

Machmudah, S., et al., Lycopene extraction from tomato peel by-product containing tomato seed using supercritical carbon dioxide. Journal of Food Engineering, 2012. 108(2): p. 290-296.

Ahmed, Z., et al., Extraction and Modeling of Algerian Rosemary Essential Oil Using Supercritical CO2: Effect of Pressure and Temperature. Energy Procedia, 2012. 18: p. 1038-1046.

Hasmida, et al., Solubility correlation of gall (Quercus infectoria) extract in supercritical CO2 using semi‐empirical equations. Asia-Pacific Journal of Chemical Engineering, 2017. 12(5): p. 790-797.

Hasmida, M., et al., Total phenolic content and antioxidant activity of quercus infectoria galls using supercritical CO2 extraction technique and its comparison with soxhlet extraction. Pertanika Journal of Science & Technology, 2015. 23(2): p. 287-295.

Molino, A., et al., Extraction of astaxanthin and lutein from microalga Haematococcus pluvialis in the red phase using CO2 supercritical fluid extraction technology with ethanol as co-solvent. Marine drugs, 2018. 16(11): p. 432.

Putra, N.R., et al., Recovery and solubility of flavonoid and phenolic contents from Arachis Hypogea in supercritical carbon dioxide assisted by ethanol as cosolvent. Journal of Food Processing and Preservation, 2020: p. e14768.

Ouédraogo, J.C.W., et al., Enhanced extraction of flavonoids from Odontonema strictum leaves with antioxidant activity using supercritical carbon dioxide fluid combined with ethanol. The Journal of Supercritical Fluids, 2018. 131: p. 66-71.

Spinelli, S., et al., Supercritical carbon dioxide extraction of brewer's spent grain. The Journal of Supercritical Fluids, 2016. 107: p. 69-74.

Maran, J.P., et al., Box-Behnken design based multi-response analysis and optimization of supercritical carbon dioxide extraction of bioactive flavonoid compounds from tea (Camellia sinensis L.) leaves. Journal of Food Science and Technology, 2015. 52(1): p. 92-104.

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Published

16-05-2022