Supercritical Carbon Dioxide Extraction of Hevea Brasiliensis Seeds: Influence of Particle Size on to Oil Seed Recovery and its Kinetic
DOI:
https://doi.org/10.11113/mjfas.v17n3.2073Keywords:
Rubber Seeds Oil, Supercritical Carbon Dioxide, Particle Size, Mass Transfer, Morphological CharacterizationAbstract
The aim of this study is to investigate the effect of particle sizes on yield, diffusivity, mass transfer and morphological characterization on extraction rate of rubber seed oil recovery by supercritical carbon dioxide (ScCO2). Pressure 30 MPa, temperature 60 oC and average particle size 500 µm gives the maximum oil recovery (34.71%), diffusivity coefficient (5.13 E-12 m2/s) and extraction rate (0.6 mg/sec). The morphological characterization of extracted rubber seeds was done on the basis of scanning electron microscopy which was parallel with the results of the effect of particle size. The results obtained from gas chromatography-mass spectrometry showed that the rubber seeds oil contained significant essential fatty acids and certain chemical constituents which are very valuable.References
Abdullah, B.M. and J. Salimon, Physicochemical characteristics of Malaysian rubber (Hevea brasiliensis) seed oil. European Journal of Scientific Research, 2009. 31(3): p. 437-445.
Shahidi, F. and U.N. Wanasundara, Omega-3 fatty acid concentrates: nutritional aspects and production technologies. Trends in food science & technology, 1998. 9(6): p. 230-240.
Talab, H.A., et al., Extraction and purification of omega‐3 fatty acids concentrate from Hypophthalmichthys molitrix oil. Nutrition & Food Science, 2010.
Uribe, J.A.R., et al., Extraction of oil from chia seeds with supercritical CO2. The Journal of Supercritical Fluids, 2011. 56(2): p. 174-178.
Hatami, T., M.A.A. Meireles, and O.N. Ciftci, Supercritical carbon dioxide extraction of lycopene from tomato processing by-products: Mathematical modeling and optimization. Journal of Food Engineering, 2019. 241: p. 18-25.
Starmans, D.A. and H.H. Nijhuis, Extraction of secondary metabolites from plant material: a review. Trends in Food Science & Technology, 1996. 7(6): p. 191-197.
Danlami, J.M., et al., A parametric investigation of castor oil (Ricinus comminis L) extraction using supercritical carbon dioxide via response surface optimization. Journal of the Taiwan Institute of Chemical Engineers, 2015. 53: p. 32-39.
Duba, K. and L. Fiori, Supercritical CO2 extraction of grape seeds oil: scale-up and economic analysis. International Journal of Food Science & Technology, 2019. 54(4): p. 1306-1312.
Özkal, S.G. and M.E. Yener, Supercritical carbon dioxide extraction of flaxseed oil: Effect of extraction parameters and mass transfer modeling. The Journal of Supercritical Fluids, 2016. 112: p. 76-80.
Bilgiç-Keleş, S., et al., Response surface optimization and modelling for supercritical carbon dioxide extraction of Echium vulgare seed oil. Journal of Supercritical Fluids, 2019. 143: p. 365-369.
Naeem, M.A., H.A. Zahran, and M.M. Hassanein, Evaluation of green extraction methods on the chemical and nutritional aspects of roselle seed (Hibiscus sabdariffa L.) oil. OCL, 2019. 26: p. 33.
dos Santos, L.C., et al., Solubility of passion fruit (Passiflora edulis Sims) seed oil in supercritical CO2. Fluid Phase Equilibria, 2019. 493: p. 174-180.
Belayneh, H.D., et al., Ethanol-Modified Supercritical Carbon Dioxide Extraction of the Bioactive Lipid Components of Camelina sativa Seed. Journal of the American Oil Chemists' Society, 2017. 94(6): p. 855-865.
Putra, N.R., et al., Extraction of peanut skin oil by modified supercritical carbon dioxide: Empirical modelling and optimization. Separation Science and Technology, 2018. 53(17): p. 2695-2703.
Crank, J., The mathematics of diffusion. 1979: Oxford university press.
Aris, N.A., et al., Effect of particle size and co-extractant in Momordica charantia extract yield and diffusion coefficient using supercritical CO2. Malaysian Journal of Fundamental and Applied Sciences, 2018. 14(3): p. 368-373.
Bimakr, M., et al., Optimization of Supercritical Carbon Dioxide Extraction of Bioactive Flavonoid Compounds from Spearmint (Mentha spicata L.) Leaves by Using Response Surface Methodology. Food and Bioprocess Technology, 2012. 5(3): p. 912-920.
Coelho, J., et al., Supercritical carbon dioxide extraction of Foeniculum vulgare volatile oil. Flavour and Fragrance Journal, 2003. 18(4): p. 316-319.
Han, X., et al., Extraction of safflower seed oil by supercritical CO2. Journal of food engineering, 2009. 92(4): p. 370-376.
Al-Rawi, S.S., et al., Comparison of yields and quality of nutmeg butter obtained by extraction of nutmeg rind by soxhlet and supercritical carbon dioxide (SC-CO2). Journal of food engineering, 2013. 119(3): p. 595-601.
Rahman, N.N.A., et al., Supercritical carbon dioxide extraction of the residual oil from palm kernel cake. Journal of Food Engineering, 2012. 108(1): p. 166-170.
Putra, N.R., et al., Effect of particle size on yield extract and antioxidant activity of peanut skin using modified supercritical carbon dioxide and soxhlet extraction. Journal of Food Processing and Preservation, 2018. 42(8): p. e13689.
Putra, N., et al. Effects of process parameters on peanut skins extract and CO2 diffusivity by supercritical fluid extraction. in IOP Conference Series: Materials Science and Engineering. 2018. IOP Publishing.
Putra, N.R., et al., Comparison extraction of peanut skin between CO2 supercritical fluid extraction and soxhlet extraction in term of oil yield and catechin. Pertanika Journal of Science & Technology, 2018. 26(2).
Lee, W.J., et al., Solubility of red palm oil in supercritical carbon dioxide: Measurement and modelling. Chinese Journal of Chemical Engineering, 2017.
Degano, C., et al., Seed characterization and scanning electron microscope (SEM) morphology of the testa of three groups of Argentine Opuntia ficus-indica (Cactaceae). J. PACD, 1997. 2: p. 103-113.
Rubio-Rodríguez, N., et al., Production of omega-3 polyunsaturated fatty acid concentrates: a review. Innovative Food Science & Emerging Technologies, 2010. 11(1): p. 1-12.
Eckert, G.P., et al., Plant derived omega-3-fatty acids protect mitochondrial function in the brain. Pharmacological research, 2010. 61(3): p. 234-241.
Venegas-Calerón, M., O. Sayanova, and J.A. Napier, An alternative to fish oils: metabolic engineering of oil-seed crops to produce omega-3 long chain polyunsaturated fatty acids. Progress in lipid research, 2010. 49(2): p. 108-119.