Tea waste/carbon black hybrid filled natural rubber composites

Authors

  • Nabil Hayeemasae Prince of Songkla University
  • Hanafi Ismail Universiti Sains Malaysia

DOI:

https://doi.org/10.11113/mjfas.v16n6.1897

Keywords:

Natural Rubber, Tea Waste, Carbon Black, Composite

Abstract

This paper aimed to present the potential use of tea waste (TW) as an alternative filler for natural rubber (NR). Because of the bigger particle size of TW and is considered to be in a class of non-reinforcing filler. Carbon black (CB) was then introduced as secondary filler for NR matrix. This is to improve the performance of the composite while maintaining the suitable amount of TW. TW was fixed at 30 parts per hundred rubber (phr) where the CB was varied from 10 – 30 phr. Incorporation of CB in the hybrid system can fasten the curing process of the composites, as the scorch and curing times increased with increasing the CB contents. CB has greatly influenced the maximum torque, tensile strength and tensile modulus due to its better rubber-filler interaction within the rubber matrix. However, the elongation at break of the composites drop continuously with the addition of the CB. This is simply due to dilution effect of the composite which refers to the less amount of flexible phase. The enhanced performance of the composite in the presence of CB can be verified by the calculation of rubber-filler interaction (Qf/Qg) values, indicating higher rubber-filler interaction when higher amount of CB was used. Apart from that, the images obtained from scanning electron microscope (SEM) also provided some evidence relating to the tensile properties observed. From the experimental results, hybridization of 30/20 phr/phr of TW and CB is highly suggested to gain the synergistic strength and processing safety.

References

Y. Chen, L. Wang, Z. Wu, J. Luo, B. Li, X. Huang, H. Xue, J. Gao. Super-hydrophobic, durable and cost-effective carbon black/rubber composites for high performance strain sensors, Composites Part B: Engineer. 176 (2019) 107358.

X. Fan, H. Xu, Q. Zhang, Y. Song, Q. Zheng. Insight into the weak strain overshoot of carbon black filled natural rubber, Polym. 167 (2019) 109-117.

N. Hayeemasae, S.Z. Salleh, H. Ismail. Using chloroprene rubber waste in rubber blends: optimizing performance by adding fillers, Green. Mater. 7 (2019) 156-167.

N. Hayeemasae, L.W. Song, H. Ismail. Sustainable use of eggshell powder in the composite based on recycled polystyrene and virgin polystyrene mixture, Intern. J. Polym. Anal. Charac. 24 (2019) 266-275.

J.A. Fiorote, A.P. Freire, D. de Sousa Rodrigues, M.A. Martins, L. Andreani, L.F. Valadares. Preparation of Composites from Natural Rubber and Oil Palm Empty Fruit Bunch Cellulose: Effect of Cellulose Morphology on Properties, Biores. 14 (2019) 3168-3181.

A. Kumagai, N. Tajima, S. Iwamoto, T. Morimoto, A. Nagatani, T. Okazaki, T. Endo. Properties of natural rubber reinforced with cellulose nanofibers based on fiber diameter distribution as estimated by differential centrifugal sedimentation, Intern. J. Bio. Macro. 121 (2019) 989-995.

M.P. Bernal, S.G. Sommer, D. Chadwick, C. Qing, L. Guoxue, F.C. Michel. Chapter Three - Current Approaches and Future Trends in Compost Quality Criteria for Agronomic, Environmental, and Human Health Benefits, in: D.L.B.T.-A. in A. Sparks (Ed.), Academic Press, 2017: pp. 143–233.

M.T. Uddin, M.A. Islam, S. Mahmud, M. Rukanuzzaman. Adsorptive removal of methylene blue by tea waste, J. Hazard. Mater. 164 (2009) 53-60.

O.H. Yeoh. Characterization of elastic properties of carbon-black-filled rubber vulcanizates, Rubb. Chem. Technol. 63 (1990) 792-805.

A. Medalia. Effect of carbon black on dynamic properties of rubber vulcanizates, Rubb. Chem. Technol. 51 (1978) 437-523.

A.R. Payne. The dynamic properties of carbon black‐loaded natural

rubber vulcanizates. Part I, J. App. Polym. Sci. 6 (1962) 57-63.

O. Lorenz, C. Parks. The crosslinking efficiency of some vulcanizing agents in natural rubber, J. Polym. Sci. 50 (1961) 299-312.

C. Parks, O. Lorenz. Crosslinking efficiency in the reaction of dicumyl peroxide with dimethyloctadiene, J. Polym. Sci. 50 (1961) 287-298.

L. Tian, B. Shen, H. Xu, F. Li, Y. Wang, S. Singh. Thermal behavior of waste tea pyrolysis by TG-FTIR analysis, Energy. 103 (2016) 533-542.

S. Baccaro, F. Cataldo, A. Cecilia, A. Cemmi, F. Padella, A. Santini. Interaction between reinforce carbon black and polymeric matrix for industrial applications, Nucl. Instrum. Methods Phys. Res. B. 208 (2003) 191-194.

H. Ismail, A. Ramly, N. Othman. The effect of carbon black/multiwall carbon nanotube hybrid fillers on the properties of natural rubber nanocomposites, Polym.-Plas. Technol. Engineer. 50 (2011) 660-666.

P. Khizhnyak, A. Chechetkin, A. Glybin. Thermal conductivity of carbon black, J. Engineer. Phys. 37 (1979) 1073-1075.

Y. Xie, C.A. Hill, Z. Xiao, H. Militz, C. Mai. Silane coupling agents used for natural fiber/polymer composites: A review, Composites Part A: App. Sci. Manufac. 41 (2010) 806-819.

I. Surya, H. Ismail, A. Azura. The effect of alkanolamide loading on properties of carbon black-filled natural rubber (SMR-L), epoxidised natural rubber (ENR), and styrene-butadiene rubber (SBR) compounds, Polym. Test. 42 (2015) 208-214.

J. Wang, K. Zhang, Z. Cheng, M. Lavorgna, H. Xia. Graphene/carbon black/natural rubber composites prepared by a wet compounding and latex mixing process, Plas. Rubb. Compos. 47 (2018) 398-412.

H. Zhang, Y. Wei, Z. Kang, G. Zhao, Y. Liu. Influence of partial substitution for carbon black with graphene oxide on dynamic properties of natural rubber composites, Micro. Nano. Lett. 12 (2017) 605-610.

K. Bahl, T. Miyoshi, S.C. Jana. Hybrid fillers of lignin and carbon black for lowering of viscoelastic loss in rubber compounds, Polym. 55 (2014) 3825-3835.

N. Rattanasom, T. Saowapark, C. Deeprasertkul. Reinforcement of natural rubber with silica/carbon black hybrid filler, Polym. Test. 26 (2007) 369-377.

Downloads

Published

28-12-2020