Synthesis and characterization of mixed nickel thiosemicarbazone complexes
DOI:
https://doi.org/10.11113/mjfas.v8n3.142Keywords:
2, 3, 4-trihydroxybenzaldehydethiosemicarbazone, nickel(II), triphenylphosphine, 1, 10-phenanthroline, 2-bipyridine,Abstract
Three nickel thiosemicarbazone mixed ligands complexes have been synthesized. Complexes with the formula [NiL(PPh3)]Cl, [Ni2L2(Phen)],[Ni2L2(Bpy)] (where L= 2,3,4-trihydroxybenzaldehydethiosemicarbazone, PPh3=Triphenylphosphine, Phen=1,10-phenanthroline, Bpy= 2,2 –Bipyridine)
have been characterized by IR spectroscopy, as well as elemental analysis. The structure of [NiL (PPh3)]Cl has been determined by X-ray
crystallography. The crystal structure of this complex shows that the Schiff base ligand functions as an N,O,S chelating anion to the phosphine –
coordinated nickel(II) atom, which exists as a distorted square – planar geometry.
References
G.F. de Sousa, C.A.L. Filgueiras, M.Y.Darensbourg and J.H. Reibenspies, Inorg. Chem. 31 (1992), 3044-3049.
C. Peak, S.O. Kang, J. Ko and P.J Corroll, Organometallics, 16 (1997) , 4755- 4758.
S.B. Padhye, and G.B. Kauffman, Coord. Chem. Rev., 63 (1985), 127-160.
Shawish et al. / Malaysian Journal of Fundamental & Applied Sciences Vol.8, No.3 (2012) 166-170
| 170 |
D.X. West, S.B. Padhye, P.B. Sonawane, and R.C. Chikte, Struct. Bond., 76 (1991), 1.
B. Prathima, Y. Subba Rao, S. Adinarayana Reddy, Y.P. Reddy, and A. Varada Reddy, Spectrochim. Acta Part A, 77 (2010), 248- 252.
A.G.Quiroga, J.M.Perez, E.I.Montero, D.X. West, C.Alonso, and C.N.Ranninger, J. Inorg. BioChem., 75 (1999), 293-301.
F.A.French, and E.J.Blanz, J.Med.Chem., 9 (1966),585-589.
A.S.Dobek, D.L.Klayman, E.T.Dickson, J.P.Scovill, and E.C. Tramont, Antimicrob.AgentsChemother., 18 (1980), 27-36.
D.L.Klayman, A.J.Lin, and J.W.McCall, J.Med.Chem.,34 (1991), 1422-1425.
C.Shipman, H.Smith, J.C.Drach, and D.L.Klayman, Antiviral Res., 6 (1986), 197-222.
A.G. Quiroga, and C.N. Ranninger, Coord. Chem. Rev., 248 (2004), 119-133.
S.N. Pandeya, and J.R. Dimmock, Pharmazie 48 (1993), 659-666.
R. Cammack and P. van Vliet. Bioinorganic Catalysis, Marcel Dekker, New York (1999).
C. Zirngible, W. Van Dongen, B. Schworer, R. Von Bunau, M. Richter, A. Klein and R. K. Thauer, Eur. J. Biochem., 208 (1992), 511-520.
A.F. Cotton, G. Wilkinson. Advanced Inorganic Chemistry, 5th ed, John Wiley & Sons: New York, 1998.
D.X. West, A.E. Liberta, S.B. Padhye, R.C. Chikate, P.B. Sonawane, A.S. Kumbhar, and R.G. Yerande, Coord. Chem. Rev.,123 (1993), 49-71.
L.M. Venanzi, J. Chem. Soc., (1958) 719-724.
H.B. Shawish, M.J. Maah and S.W. Ng, Acta Cryst., E66 (2010), o1278.
T.S. Lobana, R. Sharma, G. Bawa, and S. Khanna, Coord Chem. Rev., 253 (2009), 977-1055.
V. Mahalingam, R. Karvembu, V. Chinnusamy and K. Natavajar, Spectrochim. Acta Part A, 64 (2006), 886-890.
M. Ali, N. Hj Ibrahim, R. Butcher, J. Jasinski, and J. Bryan, Polyhedron 17 (1998),1803-1809.
H.B. Shawish, K.W. Tan, M.J. Maah and S.W. Ng, Acta Cryst., E66 (2010), m1074.
